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Sodium sulfate, anhydrous

CAS No.: 7757-82-6

  • Molecular Formula: Na₂SO₄
  • Molecular Weight: 142.04 g/mol

Chemical type

  • Ionic salt
[1,2]

Key properties

  • Provides ionic conductivity
  • Used to minimize electrode reactions (compared to NaCl)
[1]
  • Solubility in water at 20°C: 1.354 mol/L.
  • Present in pore solution; contributes to osmotic suction.
  • Can crystallize as mirabilite (Na₂SO₄·10H₂O) or thenardite (Na₂SO₄) during phase change, leading to salt expansion.
  • At 0.5°C, the solubility is 50.6 g/L.
  • Its addition to loess increases pore solution concentration.
[2]
  • Electrolyte solution in the electrode chambers (EC) of the experimental ED setup.
[1]
  • Used to prepare saline loess samples to study salt weathering mechanisms in check dams.
  • Identified as the primary culprit for salt weathering hazards in field surveys of loess check dams in northern Shaanxi.
[2]

Classification by use

  • Supporting electrolyte in electrochemical systems
[1]
  • Chemical used in geotechnical/civil engineering research
[2]

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  1. [Cite:1] Voltage optimization strategy to reduce electric field non-uniformity and improve efficiency in electrodialysis systems, Electrochemistry Communications, Volume 183, February 2026, 108104
  2. [Cite:2] Evaluation of the relationship between freezing point and suction of sodium sulfate loess near 0°C, Soils and Foundations, Volume 66, Issue 2, April 2026, 101753