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Methanoic acid

CAS No.: 64-18-6

  • Molecular Formula: CH₂O₂
  • Molecular Weight: 46.025 g/mol

Chemical type

  • CO₂ hydrogenation product
[1]
  • Carboxylic acid (shortest chain)
[2]

Key properties

  • Liquid organic acid
  • Can act as hydrogen carrier
[1]
  • Strong intermolecular hydrogen bonding
  • Forms cyclic dimers in vapor phase
  • Freezes at 8.3°C
  • Thermally decomposes above 160°C
  • High volumetric hydrogen density
  • Liquid at near-ambient conditions
  • Complex phase behavior influencing vapor-liquid equilibria, densities, and vaporization enthalpies
[2]
  • Chemical intermediate
  • Potential energy storage molecule
  • Produced via low-hydrogen stoichiometry routes
[1]
  • Sustainable chemical intermediate for synthesis of esters, formates, and derivatives
  • Preservative and processing aid in food, leather, and textile industries
  • Reducing agent in chemical processes
  • Liquid hydrogen carrier (catalytically decomposes to H₂ and CO₂ in fuel cells)
  • Working fluid in thermodynamic cycles such as high-temperature heat pumps and Rankine cycles
  • Product from CO₂ electrochemical reduction for carbon utilization
[2]

Classification by use

  • Chemicals used as hydrogen carriers
  • Chemicals used as intermediates
[1]
  • Chemicals used as hydrogen carriers
  • Chemicals used in carbon capture and utilization (CCU)
[2]

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  1. [Cite:1] Recent progress in microporous membrane reactors for catalytic conversion CO2 into value-added chemicals, Advanced Membranes, Volume 7, June 2026, 100190
  2. [Cite:2] Thermodynamic Modeling of Formic Acid with SAFT-VR Mie DBD for Energy Applications: Heat Pumps, Rankine Cycles, and CO₂ Electrochemical Reduction, Fluid Phase Equilibria, 5 February 2026, 114692