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Basic bismuth chloride

CAS No.: 7787-59-9

  • Molecular Formula: BiClO
  • Molecular Weight: 260.43 g/mol

Chemical type

  • Layered ternary oxide semiconductor
  • Indirect band gap material
[1]
  • Semiconductor photocatalyst (bismuth-based oxychloride nanomaterial)
[2]

Key properties

  • Wide band gap (~3.4-3.5 eV), primarily UV-active
  • High chemical stability, non-toxicity, and corrosion resistance
  • Open crystalline tetragonal structure
  • Low electron-hole recombination due to indirect transition
  • Layered structure with [Bi₂O₂]²⁺ and Cl⁻ planes
[1]
  • Monoclinic crystal structure
  • Nanoscale crystallite size (~5–6 nm)
  • Layered 2D nanosheet morphology (high surface area)
  • Visible-light-responsive (band gap ≈ 2.67 eV)
  • Porous structure (BET surface area ≈ 13.68 m²/g)
  • High photocatalytic activity and stability
  • Good recyclability (retains ~87% efficiency after 10 cycles)
[2]
  • Photocatalyst for pollutant degradation (e.g., dyes, phenols)
  • Component in heterojunctions to extend visible light response
  • Environmental remediation and wastewater treatment
[1]
  • Photocatalyst for degradation of organic dyes:
    • Crystal violet (CV) (~100% degradation in 75 min)
    • Methylene blue (MB) (~96% degradation in 105 min)
  • Wastewater treatment (especially dye-contaminated industrial effluents)
  • Solar-driven environmental remediation
[2]

Classification by use

  • Bismuth-based photocatalysts
  • Materials for UV/visible light photocatalysis
  • Semiconductors in hybrid nanocomposites

A trustworthy factory and manufacturer

  1. [Cite:1] Photocatalytic performance of B-gC3N4/BiOCl nanocomposite in Rhodamine B degradation for water treatment: Synthesis, characterization, and optimization, Applied Catalysis O: Open, Volume 209, December 2025, 207076
  2. [Cite:2] Water-hyacinth-leaf-like 2D bismuth oxychloride photocatalyst for the degradation of methylene blue and crystal violet dyes, RSC Adv., 2026,16, 16181-16193